Nu Instruments | Low Backgrounds with Noblesse  

This application note explains how new source materials and cleaning methods reduce mass 36 background in Noblesse. It focuses on H³⁵Cl interference and its importance for ⁴⁰Ar/³⁹Ar dating and small-sample measurement.

Mass 36 peak with and without Ar in the instrument (static and pumping, respectively). Scans made in high resolving power mode, with MRP ~6000 and sensitivity ~30000 atoms/cps, in order to observe the H35Cl.

Mass 36 background is important in ⁴⁰Ar/³⁹Ar dating because ³⁶Ar is used to correct for atmospheric contamination. The note explains that the mass 36 peak may include ³⁶Ar, H³⁵Cl and C₃, with C₃ easily resolved by Noblesse.


Following developments in source materials and cleaning methods, Noblesse achieved very low mass 36 backgrounds. The note reports H³⁵Cl interference as low as 2 x 10⁻¹⁵ ccSTP, measured both while pumping and in static mode with Ar present.


For small samples, this level of H³⁵Cl interference is similar to the uncertainty in the ³⁶Ar measurement. For larger samples, it is expected to be lost in the measurement noise, supporting practical lower-resolution operation in many cases.

 

Noblesse Noble Gas MS Instrument

Key Takeaways:

  • New materials and cleaning methods reduce mass 36 background.
  • H³⁵Cl interference can be as low as 2 x 10⁻¹⁵ ccSTP.
  • Low backgrounds support accurate ³⁶Ar correction in Ar dating.
Man adjusts part of mass spec instrument

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