Nu Instruments | Advantages of Noblesse HR for ⁴⁰Ar/³⁹Ar Dating

This application note explains why high mass resolving power is important for ⁴⁰Ar/³⁹Ar dating. It focuses on resolving carbon-based interferences, measuring ³⁶Ar accurately and understanding uncertainty in age calculations.

Mass resolving power (MRP) describes ion beam width. It corresponds to the width of the side of the peak in the mass scan. If the beam is narrower, the peak sides – formed by sweeping the beam over the edges of the collector slit – will be steeper. Mass Resolution (=MR) depends on total width of the peak, and hence on the slit width, as well.

Noblesse HR provides enhanced mass resolving power for Ar isotope measurements. The note explains how the instrument resolves carbon-based interferences and supports measurement of ³⁶Ar, which is often critical in ⁴⁰Ar/³⁹Ar dating.

 

A key point is that edge resolution can be preferable to true resolution for Ar isotope work. Edge resolution allows practical measurement of combined peaks while retaining enough peak flat for calibration and correction.

 

The note highlights the importance of ³⁶Ar because it is used to correct for trapped air. In many samples, uncertainty in ³⁶Ar can dominate final age uncertainty, making high-resolution measurement essential.

 

Noblesse Noble Gas MS Instrument

Key Takeaways:

  • Noblesse HR resolves carbon-based interferences at Ar masses.
  • ³⁶Ar measurement is often critical to accurate ⁴⁰Ar/³⁹Ar dating.
  • Edge resolution can be more practical than true resolution for Ar measurement.
Man adjusts part of mass spec instrument

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